Welcome to B:bob:B! You don’t mention what version you are using…there is a CMS universe with the mosr recent version, which would be easier than using Query Builder.
The CMS query language is SQL-ish, but does not support joins which would be necessary to produce your desired result in a single query.
This will require two steps:
select si_id,si_name,si_userfullname,si_creation_time,si_email_address,si_usergroups from ci_systemobjects where si_kind = 'user'
This will produce a list of all users. Next, get a list of all groups:
select si_id,si_name from ci_systemobjects wehre si_kind = 'usergroup'
You’ll then need to cross-reference the values in the SI_USERGROUPS property from the first step with the SI_ID values in the second. This will give you a list of the groups that each user is a member of.